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Sample text

Other areas where standing water can cause corrosion because of differential aeration are the low points in vent systems, sump drain lines, refueling seals and skirts, the sand pocket area, and penetration sleeves. The potential for this form of corrosion exists at the base of the vessel where the shell is embedded in concrete. The interior and exterior concreteacts as a coating to resist corrosion of the embedded shell. However, during startup and shutdown, differences in thermal expansion rates may deteriorate the sealant and create a gap between the shell and the concrete.

For example, a difference in oxygen concentration between two surfaces or two sites on the same 21 NUREG/CR-5314 Corrosion Damage Some of these mechanisms, for example, pithowever, they warrant separate consideration because environments corrosion damting and the crevice corrosion,causing are closely related; age and the susceptible sites can be different. The relationships between these mechanisms are identified in the following discussions. The similarities and differences between pitting and crevice / [ Metal Figure 9.

These researchers also assume that crevice corrosion initiates from The basic mechanism of crevice corrosion can be explained as follows. Initially, these reactions occur uniformly over the entire surface, including both the interior and exterior of the crevice. Both oxygen reduction and metal dissolution take place in the crevice. After a short time, the oxygen pits formed inside the crevice where passivity initially breaks down. Also, from an electrochemistry point of view, both crevice corrosion and pitting are identical, except crevice corrosion is associated with a longei diffusion path (SzklarskaSmialowska 1986).

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